Enantioselective syntheses and configuration assignments of gamma-chiral butenolides from Plagiomnium undulatum : butenolide synthesis from tetronic acids
Both enantiomers of the gamma-chiral alpha,beta-dimethylated butyrolactones nat-1 and nat-2 from the moss Plagiomnium undulatum were synthesized stereoselectively through butenolides and tetronic acids, respectively. The configuration of the natural products was determined by GLC comparisons with mono(3-O-acetyl-6-O-tert-butyldimethylsilyl-2-O-methyl)hexakis(6-O-tert-butyldimethylsilyl-2,3-di-O-methyl)-beta-cyclodextrin as a stationary phase.
Medienart: |
Artikel |
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Erscheinungsjahr: |
2005 |
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Erschienen: |
2005 |
Enthalten in: |
Zur Gesamtaufnahme - volume:11 |
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Enthalten in: |
Chemistry (Weinheim an der Bergstrasse, Germany) - 11(2005), 7 vom: 18. März, Seite 2154-62 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Kapferer, Tobias [VerfasserIn] |
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Themen: |
4-Butyrolactone |
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Anmerkungen: |
Date Completed 03.08.2006 Date Revised 16.11.2017 published: Print Citation Status MEDLINE |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM153713909 |
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245 | 1 | 0 | |a Enantioselective syntheses and configuration assignments of gamma-chiral butenolides from Plagiomnium undulatum |b butenolide synthesis from tetronic acids |
264 | 1 | |c 2005 | |
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500 | |a Date Completed 03.08.2006 | ||
500 | |a Date Revised 16.11.2017 | ||
500 | |a published: Print | ||
500 | |a Citation Status MEDLINE | ||
520 | |a Both enantiomers of the gamma-chiral alpha,beta-dimethylated butyrolactones nat-1 and nat-2 from the moss Plagiomnium undulatum were synthesized stereoselectively through butenolides and tetronic acids, respectively. The configuration of the natural products was determined by GLC comparisons with mono(3-O-acetyl-6-O-tert-butyldimethylsilyl-2-O-methyl)hexakis(6-O-tert-butyldimethylsilyl-2,3-di-O-methyl)-beta-cyclodextrin as a stationary phase | ||
650 | 4 | |a Journal Article | |
650 | 4 | |a Research Support, Non-U.S. Gov't | |
650 | 7 | |a Furans |2 NLM | |
650 | 7 | |a Lactones |2 NLM | |
650 | 7 | |a butenolide |2 NLM | |
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700 | 1 | |a Herzig, Axel |e verfasserin |4 aut | |
700 | 1 | |a König, Wilfried A |e verfasserin |4 aut | |
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