Influence of anionic ligands (X) on the nature and magnetic properties of dinuclear LCuDgX3.nH2O complexes (LH2 standing for tetradentate Schiff base ligands deriving from 2-hydroxy-3-methoxybenzaldehyde and X being Cl, N3C2, and CF3COO)
The monometallic precursor L1Cu (L1H2 standing for 1,3-bis((3-methoxysalicylidene)amino)-2,2'-dimethylpropane) reacts with GdC13 x 6H2O to afford a dinuclear complex which crystallizes in the orthorhombic space group Pca2(1) (No. 29) in a cell having the dimensions a = 9.0246(11) A, b = 16.5198(14) A, c = 20.286(2) A, and Z = 4. Analysis of the structural data shows that it may be formulated as [L1CuCl2Gd(H2O)4]Cl x 2H2O. The cationic dinuclear unit possesses a CuO2Gd bridging core which is almost planar. The complex displays a ferromagnetic interaction (10.1 cm(-1) which is the largest yet reported for a structurally characterized dinuclear (Cu-Gd) complex. Lower magnetic interactions are observed for neutral L1CuGdX3 x H2O complexes (X = N3C2, CF3COO). Consideration of the magnetic and structural data obtained for various dinuclear (Cu-Gd) complexes leads to a correlation between the magnitude of the magnetic interaction and the exponential of the dihedral angle between the two halves of the CuO2Gd bridging core.
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Artikel |
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Erscheinungsjahr: |
2000 |
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Erschienen: |
2000 |
Enthalten in: |
Zur Gesamtaufnahme - volume:39 |
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Enthalten in: |
Inorganic chemistry - 39(2000), 2 vom: 24. Jan., Seite 165-8 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Costes, J P [VerfasserIn] |
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Anmerkungen: |
Date Completed 29.03.2001 Date Revised 14.08.2019 published: Print Citation Status PubMed-not-MEDLINE |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM111825784 |
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100 | 1 | |a Costes, J P |e verfasserin |4 aut | |
245 | 1 | 0 | |a Influence of anionic ligands (X) on the nature and magnetic properties of dinuclear LCuDgX3.nH2O complexes (LH2 standing for tetradentate Schiff base ligands deriving from 2-hydroxy-3-methoxybenzaldehyde and X being Cl, N3C2, and CF3COO) |
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500 | |a Date Completed 29.03.2001 | ||
500 | |a Date Revised 14.08.2019 | ||
500 | |a published: Print | ||
500 | |a Citation Status PubMed-not-MEDLINE | ||
520 | |a The monometallic precursor L1Cu (L1H2 standing for 1,3-bis((3-methoxysalicylidene)amino)-2,2'-dimethylpropane) reacts with GdC13 x 6H2O to afford a dinuclear complex which crystallizes in the orthorhombic space group Pca2(1) (No. 29) in a cell having the dimensions a = 9.0246(11) A, b = 16.5198(14) A, c = 20.286(2) A, and Z = 4. Analysis of the structural data shows that it may be formulated as [L1CuCl2Gd(H2O)4]Cl x 2H2O. The cationic dinuclear unit possesses a CuO2Gd bridging core which is almost planar. The complex displays a ferromagnetic interaction (10.1 cm(-1) which is the largest yet reported for a structurally characterized dinuclear (Cu-Gd) complex. Lower magnetic interactions are observed for neutral L1CuGdX3 x H2O complexes (X = N3C2, CF3COO). Consideration of the magnetic and structural data obtained for various dinuclear (Cu-Gd) complexes leads to a correlation between the magnitude of the magnetic interaction and the exponential of the dihedral angle between the two halves of the CuO2Gd bridging core | ||
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