Synthesis and characterization of the dodecanuclear heterobimetallic Mo—Cu—S cage cluster: (Ph4P)2[{Mo2Cu2O2S2(S2)2}3(μ6-S)]
Abstract The complex (Ph4P)2[Mo2S2O2(S2)(S4)] reacts with CuBr to give the dodecanuclear heterobimetallic Mo—Cu—S cage cluster: (Ph4P)2[{Mo2Cu2O2S2(S2)2}3(μ6-S)] (1), which crystallizes in the triclinic space group P1¯, a = 14.445(5), b = 15.396(5), c = 18.858(5) Å, α = 103.12(3), β = 101.93(2), γ = 113.92(3)°, and V = 3517(2) Å3 for Z = 2. The anion 1 can be described as a cage with S2− at the center binding to six Cu atoms; the cage has two big windows each composed of a puckered Cu3S6 9-membered ring..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
1999 |
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| Erschienen: |
1999 |
| Reproduktion: |
Springer Online Journal Archives 1860-2002 |
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| Enthalten in: |
Zur Gesamtaufnahme - volume:29 |
| Enthalten in: |
Journal of chemical crystallography - 29(1999) vom: Mai, Seite 581-586 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Lin, Ping [Sonstige Person] |
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| Links: |
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| Umfang: |
6 |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLEJ197575250 |
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| 245 | 1 | 0 | |a Synthesis and characterization of the dodecanuclear heterobimetallic Mo—Cu—S cage cluster: (Ph4P)2[{Mo2Cu2O2S2(S2)2}3(μ6-S)] |
| 264 | 1 | |c 1999 | |
| 300 | |a 6 | ||
| 336 | |a nicht spezifiziert |b zzz |2 rdacontent | ||
| 337 | |a nicht spezifiziert |b z |2 rdamedia | ||
| 338 | |a nicht spezifiziert |b zu |2 rdacarrier | ||
| 520 | |a Abstract The complex (Ph4P)2[Mo2S2O2(S2)(S4)] reacts with CuBr to give the dodecanuclear heterobimetallic Mo—Cu—S cage cluster: (Ph4P)2[{Mo2Cu2O2S2(S2)2}3(μ6-S)] (1), which crystallizes in the triclinic space group P1¯, a = 14.445(5), b = 15.396(5), c = 18.858(5) Å, α = 103.12(3), β = 101.93(2), γ = 113.92(3)°, and V = 3517(2) Å3 for Z = 2. The anion 1 can be described as a cage with S2− at the center binding to six Cu atoms; the cage has two big windows each composed of a puckered Cu3S6 9-membered ring. | ||
| 533 | |f Springer Online Journal Archives 1860-2002 | ||
| 700 | 1 | |a Lin, Ping |4 oth | |
| 700 | 1 | |a Wu, Xintao |4 oth | |
| 700 | 1 | |a Chen, Ling |4 oth | |
| 700 | 1 | |a Du, Wenxin |4 oth | |
| 700 | 1 | |a Zheng, Yifan |4 oth | |
| 773 | 0 | 8 | |i in |t Journal of chemical crystallography |d 1971 |g 29(1999) vom: Mai, Seite 581-586 |w (DE-627)NLEJ188990267 |w (DE-600)1491232-6 |x 1572-8854 |7 nnns |
| 773 | 1 | 8 | |g volume:29 |g year:1999 |g month:05 |g pages:581-586 |g extent:6 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1023/A:1009552904012 |
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