Crystal Structure of Mixed Crystals of the Tetra(n-butyl)ammonium Salts of cis-Tetrafluorophthalocyaninato(2-)tantalate(V) and cis-Trifluorophthalocyaninato(2-)tantalate(IV)
cis-Trichlorophthalocyaninato(2-)tantalate(V) reacts with excess tetra(n-butyl)ammonium fluoride trihydrate yielding mixed crystals of the tetra(n-butyl)ammonium salts of cis-tetrafluorophthalocyaninato(2-)tantalate(V) and cis-trifluorophthalocyaninato(2-)tantalate(IV) in the ratio five to four. These crystallize in the monoclinic space group P21/ n with cell parameters: a = 13.368(2) Å, b = 13.787(2) Å, c = 23.069(3) Å, β = 93.35(1)°, Z = 4. Tav is octacoordinated with four F atoms and four Niso atoms in an antiprismatic cis-arrangement. The Tav-F distance varies from 1.919(7) to 1.966(4) Å. TaIV is heptacoordinated with three F atoms in a cis-arrangement. The TaIV-F distance varies from 1.74(1) to 1.966(4) Å. The Ta atom is located out of the centre of the N4 plane towards the F atoms by 1.234(3) Å. The Ta-N distances range from 2.261(6) to 2.310(6) Å..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
1997 |
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| Erschienen: |
1997 |
| Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
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| Enthalten in: |
Zur Gesamtaufnahme - volume:623 |
| Enthalten in: |
Zeitschrift für anorganische Chemie - 623(1997) vom: Dez., Seite 1853-1854 |
| Sprache: |
Deutsch |
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| Beteiligte Personen: |
Schweiger, Karsten [Sonstige Person] |
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| Links: |
dx.doi.org [Deutschlandweit zugänglich] |
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| Umfang: |
1 Ill. 2 |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLEJ163072817 |
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| 245 | 1 | 0 | |a Crystal Structure of Mixed Crystals of the Tetra(n-butyl)ammonium Salts of cis-Tetrafluorophthalocyaninato(2-)tantalate(V) and cis-Trifluorophthalocyaninato(2-)tantalate(IV) |
| 264 | 1 | |c 1997 | |
| 300 | |b 1 Ill. | ||
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| 337 | |a nicht spezifiziert |b z |2 rdamedia | ||
| 338 | |a nicht spezifiziert |b zu |2 rdacarrier | ||
| 520 | |a cis-Trichlorophthalocyaninato(2-)tantalate(V) reacts with excess tetra(n-butyl)ammonium fluoride trihydrate yielding mixed crystals of the tetra(n-butyl)ammonium salts of cis-tetrafluorophthalocyaninato(2-)tantalate(V) and cis-trifluorophthalocyaninato(2-)tantalate(IV) in the ratio five to four. These crystallize in the monoclinic space group P21/ n with cell parameters: a = 13.368(2) Å, b = 13.787(2) Å, c = 23.069(3) Å, β = 93.35(1)°, Z = 4. Tav is octacoordinated with four F atoms and four Niso atoms in an antiprismatic cis-arrangement. The Tav-F distance varies from 1.919(7) to 1.966(4) Å. TaIV is heptacoordinated with three F atoms in a cis-arrangement. The TaIV-F distance varies from 1.74(1) to 1.966(4) Å. The Ta atom is located out of the centre of the N4 plane towards the F atoms by 1.234(3) Å. The Ta-N distances range from 2.261(6) to 2.310(6) Å. | ||
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| 700 | 1 | |a Hückstädt, Heiner |4 oth | |
| 700 | 1 | |a Homborg, Heiner |4 oth | |
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