Unprecedented Coordination of 4,4′,5,5′-Tetramethyl-2,2′-biphosphinine Doubly Bridging over an Open Triosmium Core
The crystal structure of the novel cluster [Os3(CO)10(4,4′,5,5′-tetramethyl-2,2′-biphosphinine)] reveals an unprecedented coordination mode of the biphosphinine ligand that occupies a doubly-bridging position spanning the open osmium triangle. The cluster is photostable, pointing to a localization of the lowest-energy electronic transition largely on the negatively charged biphosphinine ligand..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2000 |
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| Erschienen: |
2000 |
| Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
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| Enthalten in: |
Zur Gesamtaufnahme - volume:2000 |
| Enthalten in: |
Berichte der deutschen chemischen Gesellschaft - 2000(2000) vom: Mai, Seite 843-845 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Bakker, Maarten J. [Sonstige Person] |
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| Links: |
dx.doi.org [Deutschlandweit zugänglich] |
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| Umfang: |
2 Ill. 3 |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLEJ162362498 |
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| 245 | 1 | 0 | |a Unprecedented Coordination of 4,4′,5,5′-Tetramethyl-2,2′-biphosphinine Doubly Bridging over an Open Triosmium Core |
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| 520 | |a The crystal structure of the novel cluster [Os3(CO)10(4,4′,5,5′-tetramethyl-2,2′-biphosphinine)] reveals an unprecedented coordination mode of the biphosphinine ligand that occupies a doubly-bridging position spanning the open osmium triangle. The cluster is photostable, pointing to a localization of the lowest-energy electronic transition largely on the negatively charged biphosphinine ligand. | ||
| 533 | |f Wiley InterScience Backfile Collection 1832-2000 | ||
| 700 | 1 | |a Bakker, Maarten J. |4 oth | |
| 700 | 1 | |a Vergeer, Frank W. |4 oth | |
| 700 | 1 | |a Hartl, František |4 oth | |
| 700 | 1 | |a Goubitz, Kees |4 oth | |
| 700 | 1 | |a Fraanje, Jan |4 oth | |
| 700 | 1 | |a Rosa, Patrick |4 oth | |
| 700 | 1 | |a Le Floch, Pascal |4 oth | |
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