Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands - Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R=2,4,6-Pri3C6H2, Cyclohexyl, Cp′=C5H4Me)Dedicated to Professor Dr. Joachim Strähle on the occasion of his 60th birthday.
[Cp′MoCl4(CH3CN) (Cp′=C5H4Me) react with 2,4,6-triisopropylphenylphosphane or cyclohexylphosphane to give the phosphane complexes [Cp′MoCl4(PH2R)] [R=2,4,6-Pri3C6H2 (1)]. 1 and 2, were characterized spectroscopically (IR, MS) and by crystal structure determinations. EPR investigations in liquid and frozen solution confirmed the presence of Mo(V) species and the data were used to analyze the spin-density distribution in the first coordination sphere..
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
1997 |
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| Erschienen: |
1997 |
| Reproduktion: |
Wiley InterScience Backfile Collection 1832-2000 |
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| Enthalten in: |
Zur Gesamtaufnahme - volume:130 |
| Enthalten in: |
Berichte der deutschen chemischen Gesellschaft - 130(1997) vom: Juni, Seite 807-812 |
| Sprache: |
Deutsch |
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| Beteiligte Personen: |
Felsberg, Reinhard [Sonstige Person] |
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| Links: |
dx.doi.org [Deutschlandweit zugänglich] |
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| Umfang: |
4 Ill. ; 2 Tab. 6 |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLEJ161578284 |
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| 245 | 1 | 0 | |a Organometallic Molybdenum(V) Complexes with Promary Phosphane Ligands - Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R=2,4,6-Pri3C6H2, Cyclohexyl, Cp′=C5H4Me)Dedicated to Professor Dr. Joachim Strähle on the occasion of his 60th birthday. |
| 264 | 1 | |c 1997 | |
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| 520 | |a [Cp′MoCl4(CH3CN) (Cp′=C5H4Me) react with 2,4,6-triisopropylphenylphosphane or cyclohexylphosphane to give the phosphane complexes [Cp′MoCl4(PH2R)] [R=2,4,6-Pri3C6H2 (1)]. 1 and 2, were characterized spectroscopically (IR, MS) and by crystal structure determinations. EPR investigations in liquid and frozen solution confirmed the presence of Mo(V) species and the data were used to analyze the spin-density distribution in the first coordination sphere. | ||
| 533 | |f Wiley InterScience Backfile Collection 1832-2000 | ||
| 700 | 1 | |a Felsberg, Reinhard |4 oth | |
| 700 | 1 | |a Blsurock, Steffen |4 oth | |
| 700 | 1 | |a Jelonek, Svea |4 oth | |
| 700 | 1 | |a Gelbrich, Thomas |4 oth | |
| 700 | 1 | |a Kirmse, Reinhard |4 oth | |
| 700 | 1 | |a Voigt, Andreas |4 oth | |
| 700 | 1 | |a Hey-Hawkins, Evamarie |4 oth | |
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