A facile method to synthesize nZVI-doped polypyrrole-based carbon nanotube for Ag(i) removal
Abstract The pollution of silver ion (Ag(i)) has become a serious environmental threat and hazard to ecosystem and human health. Thus, the nanoscale zero valent iron (nZVI)-doped polypyrrole-based carbon nanotube (nZVI/CNT) composites were synthesized by a facile method to remove Ag(i) from wastewater due to the toxicity and scarcity nature of Ag(i). In this process, $ Fe^{3+} $ initiated the self-assembly of polypyrrole tubes in the presence of methyl orange, while it also served as an iron source generated nZVI/CNTs by carbothermal reduction method. The nZVI/CNT composites exhibited a homogeneous tubular structure, and the nZVI formed were uniformly dispersed in the nZVI/CNT composites. The nZVI/CNT composites were used as an adsorbent for the removal of Ag(i) and showed a higher adsorption capacity compared to nZVI and CNTs, with a maximum adsorption capacity of 522.41 mg $ g^{−1} $. Ag(i) was adsorbed on nZVI/CNT composites by ion exchange and chelation, where Ag(i) was reduced to non-toxic Ag due to the redox reaction among pyrrolic-N, nZVI, and Ag(i). The adsorption process of Ag(i) on nZVI/CNT composites was dominated by monolayer adsorption. According to our results, nZVI/CNT composites can be used as economical treatment for wastewater containing Ag(i)..
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2023 |
|---|---|
| Erschienen: |
2023 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:12 |
|---|---|
| Enthalten in: |
Nanotechnology reviews - 12(2023), 1 vom: 25. Okt. |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Zhang, Wen-Juan [VerfasserIn] |
|---|
| Links: |
Volltext [kostenfrei] |
|---|
| BKL: |
|---|
| Anmerkungen: |
© 2023 the author(s), published by De Gruyter |
|---|
| doi: |
10.1515/ntrev-2023-0114 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
GRUY009274650 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | GRUY009274650 | ||
| 003 | DE-627 | ||
| 005 | 20231027003626.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231027s2023 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1515/ntrev-2023-0114 |2 doi | |
| 035 | |a (DE-627)GRUY009274650 | ||
| 035 | |a (DE-B1597)ntrev-2023-0114-e | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 540 |a 660 |q VZ |
| 084 | |a 50.94 |2 bkl | ||
| 084 | |a 51.00 |2 bkl | ||
| 100 | 1 | |a Zhang, Wen-Juan |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a A facile method to synthesize nZVI-doped polypyrrole-based carbon nanotube for Ag(i) removal |
| 264 | 1 | |c 2023 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a © 2023 the author(s), published by De Gruyter | ||
| 520 | |a Abstract The pollution of silver ion (Ag(i)) has become a serious environmental threat and hazard to ecosystem and human health. Thus, the nanoscale zero valent iron (nZVI)-doped polypyrrole-based carbon nanotube (nZVI/CNT) composites were synthesized by a facile method to remove Ag(i) from wastewater due to the toxicity and scarcity nature of Ag(i). In this process, $ Fe^{3+} $ initiated the self-assembly of polypyrrole tubes in the presence of methyl orange, while it also served as an iron source generated nZVI/CNTs by carbothermal reduction method. The nZVI/CNT composites exhibited a homogeneous tubular structure, and the nZVI formed were uniformly dispersed in the nZVI/CNT composites. The nZVI/CNT composites were used as an adsorbent for the removal of Ag(i) and showed a higher adsorption capacity compared to nZVI and CNTs, with a maximum adsorption capacity of 522.41 mg $ g^{−1} $. Ag(i) was adsorbed on nZVI/CNT composites by ion exchange and chelation, where Ag(i) was reduced to non-toxic Ag due to the redox reaction among pyrrolic-N, nZVI, and Ag(i). The adsorption process of Ag(i) on nZVI/CNT composites was dominated by monolayer adsorption. According to our results, nZVI/CNT composites can be used as economical treatment for wastewater containing Ag(i). | ||
| 700 | 1 | |a Ding, Ye-Zhi |4 aut | |
| 700 | 1 | |a Wang, Ya-Xian |4 aut | |
| 700 | 1 | |a Wang, You-Liang |4 aut | |
| 700 | 1 | |a Fei, Yu-Long |4 aut | |
| 700 | 1 | |a Ran, Meng-Yu |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Nanotechnology reviews |d De Gruyter, 2012 |g 12(2023), 1 vom: 25. Okt. |h Online-Ressource |w (DE-627)GRUY000007293 |w (DE-600)2646548-6 |w (DE-576)358409365 |x 2191-9097 |7 nnns |
| 773 | 1 | 8 | |g volume:12 |g year:2023 |g number:1 |g day:25 |g month:10 |
| 856 | 4 | 0 | |u https://dx.doi.org/10.1515/ntrev-2023-0114 |z kostenfrei |3 Volltext |
| 912 | |a GBV_GRUY | ||
| 912 | |a SSG-OLC-PHA | ||
| 936 | b | k | |a 50.94 |j Mikrosystemtechnik |j Nanotechnologie |q VZ |
| 936 | b | k | |a 51.00 |j Werkstoffkunde: Allgemeines |q VZ |
| 951 | |a AR | ||
| 952 | |d 12 |j 2023 |e 1 |b 25 |c 10 | ||