Crystal structure of diethyl {2,2,2-trichloro-1-[2-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)-4-methylpentanamido]ethyl}phosphonate
In the title phosphorylated compound, C20H26Cl3N2O6P, the phthalimide unit is essentially planar (r.m.s. deviation = 0.0129 Å) and the O atoms of this unit deviate from the mean plane by 0.080 (3) and 0.041 (3) Å. In the crystal, pairs of molecules are linked by N—H...O and weak C—H...O hydrogen bonds involving the same acceptor atom, forming inversion dimers. In addition, π–π stacking interactions between the phthalimide groups, with a centroid–centroid distance of 3.7736 (13) Å, and further weak C—H...O hydrogen bonds connect the inversion dimers into columns along [0\overline{1}1]..
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2018 |
|---|---|
| Erschienen: |
2018 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:74 |
|---|---|
| Enthalten in: |
Acta Crystallographica Section E: Crystallographic Communications - 74(2018), 7, Seite 915-917 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
V. S. Brovarets [VerfasserIn] |
|---|
| Links: |
doi.org [kostenfrei] |
|---|
| Themen: |
Crystal structure |
|---|
| doi: |
10.1107/S2056989018008277 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
DOAJ019302673 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | DOAJ019302673 | ||
| 003 | DE-627 | ||
| 005 | 20230502214205.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 230226s2018 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1107/S2056989018008277 |2 doi | |
| 035 | |a (DE-627)DOAJ019302673 | ||
| 035 | |a (DE-599)DOAJd9e12ef3837e48f98d3d0f02808d603d | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 050 | 0 | |a QD901-999 | |
| 100 | 0 | |a V. S. Brovarets |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Crystal structure of diethyl {2,2,2-trichloro-1-[2-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)-4-methylpentanamido]ethyl}phosphonate |
| 264 | 1 | |c 2018 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 520 | |a In the title phosphorylated compound, C20H26Cl3N2O6P, the phthalimide unit is essentially planar (r.m.s. deviation = 0.0129 Å) and the O atoms of this unit deviate from the mean plane by 0.080 (3) and 0.041 (3) Å. In the crystal, pairs of molecules are linked by N—H...O and weak C—H...O hydrogen bonds involving the same acceptor atom, forming inversion dimers. In addition, π–π stacking interactions between the phthalimide groups, with a centroid–centroid distance of 3.7736 (13) Å, and further weak C—H...O hydrogen bonds connect the inversion dimers into columns along [0\overline{1}1]. | ||
| 650 | 4 | |a crystal structure | |
| 650 | 4 | |a phtalimide derivatives | |
| 650 | 4 | |a phosphorylated compounds | |
| 653 | 0 | |a Crystallography | |
| 700 | 0 | |a O. V. Golovchenko |e verfasserin |4 aut | |
| 700 | 0 | |a E. B. Rusanov |e verfasserin |4 aut | |
| 700 | 0 | |a J. A. Rusanova |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i In |t Acta Crystallographica Section E: Crystallographic Communications |d International Union of Crystallography, 2015 |g 74(2018), 7, Seite 915-917 |w (DE-627)DOAJ000122815 |x 20569890 |7 nnns |
| 773 | 1 | 8 | |g volume:74 |g year:2018 |g number:7 |g pages:915-917 |
| 856 | 4 | 0 | |u https://doi.org/10.1107/S2056989018008277 |z kostenfrei |
| 856 | 4 | 0 | |u https://doaj.org/article/d9e12ef3837e48f98d3d0f02808d603d |z kostenfrei |
| 856 | 4 | 0 | |u http://scripts.iucr.org/cgi-bin/paper?S2056989018008277 |z kostenfrei |
| 856 | 4 | 2 | |u https://doaj.org/toc/2056-9890 |y Journal toc |z kostenfrei |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_DOAJ | ||
| 912 | |a SSG-OLC-PHA | ||
| 951 | |a AR | ||
| 952 | |d 74 |j 2018 |e 7 |h 915-917 | ||