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|a Blusch, Lina Katharina
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|a The Siamese-Twin Porphyrin and its copper and nickel complexes
|b a non-innocent twist
|c by Lina K. Blusch
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|a Cham
|b Springer International Publishing
|c 2013
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|a XVIII, 158 S.
|b Ill.
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|a Zugl.: Göttingen, Univ., Diss., 2012
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|a This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This ""Siamese-Twin Porphyrin"" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innoce
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