Organometallic chemistry : Volume 43 / editors: Nathan J. Patmore (University of Huddersfield, UK), Paul I.P. Elliott (University of Huddersfield, UK)

Cover -- Contents -- Author biographies -- Abbreviations -- Recent advances in chromiumcoordination chemistry: luminescentmaterials and photocatalysis -- 1 Introduction and scope -- 2 Notes -- 3 Photophysics of Cr(III) complexes -- 4 Homoleptic polypyridyl complexes of Cr(III) -- 5 Heteroleptic polypyridyl complexes of Cr(III) -- 5 Heteroleptic polypyridyl complexes of Cr(III) -- 7 Macrocyclic bis-cyano complexes of Cr(III) -- 8 Photoluminescent Cr(0) complexes -- 9 Cr(III) complexes in photoredox catalysis -- 10 Concluding remarks -- References.

Organometallic compounds of rutheniumand their application in chemotherapy -- 1 Introduction -- 2 Arene ruthenium with biology activity -- 2.1 Arene ruthenium with mono-dentate ligands -- 2.1.1 N-donor ligands -- 2.1.2 Phosphorus as coordinating atom -- 2.2 Arene ruthenium complexes with a bidentate ligand -- 2.2.1 N,N-bidentate ligands -- 2.2.2 N,O-bidentate ligand -- 2.2.3 Thiol ligands -- 2.3 Other complexes -- 3 Anticancer mechanism of arene ruthenium(II) complexes -- 3.1 Apoptosis inducers -- 3.2 Inhibitors against tumor migration and invasion -- 3.3 Cell phase arrest inducers.

3.4 DNA binder -- 4 Conclusions and outlook -- Acknowledgments -- References -- Multinuclear catalysts for the ring-openingpolymerisation of cyclic esters -- 1 Introduction -- 2 Ring opening polymerisation of lactide -- 2.1 Homometallic catalysts for the ROP of lactide -- 2.1.1 Group I and II and Zn catalysts -- 2.1.2 Main group catalysts -- 2.1.3 Transition metal catalysts -- 2.1.4 f-block catalysts -- 2.2 Heterometallic catalysts for the ROP of lactide -- 3 Ring opening polymerisation of other cyclic esters -- 3.1 Homometallic catalysts for the ROP of cyclic esters.

3.1.1 Group I and II and Zn catalysts -- 3.1.2 Main group catalysts -- 3.1.3 Transition metal catalysts for the ROP of cyclic esters -- 3.2 Heterometallic catalysts -- 4 Conclusions -- References -- Design of gadolinium complexes asmagnetic resonance imaging contra stagents -- 1 Introduction -- 2 Principles of magnetic resonance imaging -- 2.1 How MRI works -- 2.2 Relaxation times T1/T2 -- 3 How MRI contrast agents work -- 3.1 Properties of Gd3+/clinical GdCAs/toxicity -- 3.2 Commercial GdCAs -- Advances in the chemistry of metal-metalquadruple bonds 2015-2020 -- 1 Introduction.

1.1 The quadruple bond -- 2 Electron transfer -- 2.1 Ground state mixed valency -- 2.2 Ligand-based redox activity -- 2.3 Mixed valency across hydrogen bonds -- 2.4 Excited state electron transfer -- 3 Reactivity -- 3.1 The quintuple bond and varying bond order through reactivity -- 3.2 Reactivity of quadruply bonded complexes -- 3.3 Catalysis -- 4 Coordination chemistry -- 4.1 Multimetallic structures and extended arrays -- 4.2 Tuning electronic structure -- 4.3 Lewis acids at the axial position: extended metal-atom chains -- 5 Conclusions -- References.

Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. The reviews range in scope and include recent advances in chromium coordination chemistry, borohydride and borane ligand architectures supported by heterocyclic units and discussion on behaviours of novel ruthenium(II) complexes. This volume is a key reference for researchers in academic and industrial settings.

Medienart:	E-Book

Erscheinungsjahr:	2021
Erschienen:	Cambridge: Royal Society of Chemistry ; 2021

Reihe:	Organometallic chemistry - volume 43 A specialist periodical report

Sprache:	Englisch

Beteiligte Personen:	Patmore, Nathan J. [HerausgeberIn] Elliott, Paul I. P. [HerausgeberIn]

Links:	doi.org [lizenzpflichtig] pubs.rsc.org

ISBN:	978-1-78801-707-7 978-1-78801-708-4

BKL:	35.60 / Metallorganische Verbindungen 35.43 / Koordinationsverbindungen / Komplexchemie
Themen:	Electronic books Metallorganische Chemie Organometallic chemistry Periodicals Rutheniumkomplexe

Umfang:	1 Online-Ressource(xviii, 228 Seiten)

doi:	10.1039/9781788017077

funding:
Förderinstitution / Projekttitel:

PPN (Katalog-ID):	1697197647