Analytical Electrogenerated Chemiluminescence : From Fundamentals to Bioassays
Book is ideal for graduate students, academics and researchers in industry looking for a comprehensive guide to the different aspects of electrogenerated chemiluminescence..
Cover -- Preface -- Contents -- Chapter 1 Introduction and Overview of Electrogenerated Chemiluminescence -- 1.1 Introduction -- 1.2 Fundamentals of Electrochemistry and Photophysics for ECL -- 1.2.1 Basic Electrochemical Principles -- 1.2.2 Basic Photophysical Principles -- 1.2.3 Energetics and Kinetics -- 1.3 Mechanistic Pathways of ECL -- 1.3.1 Electron-transfer Reactions Involving the Luminophore -- 1.3.2 Bond-breaking Reactions Within the Luminophore Frame -- 1.3.3 Hot Electron-induced ECL -- 1.4 Key Protagonists in the ECL -- 1.4.1 Luminophores -- 1.4.2 Coreactants -- 1.4.3 Electrode Materials -- 1.5 Analytical Applications -- 1.5.1 Analytical Strategies -- 1.5.2 Bioassays -- 1.6 Conclusion -- References -- Chapter 2 Energetic and Kinetic Aspects of ECL Generation -- 2.1 Introduction -- 2.2 Energetics of ECL Reactants Annihilation -- 2.3 ECL Emission from the Lowest Excited Triplet State -- 2.4 ECL Emission from the Lowest Excited Singlet State -- 2.5 Concluding Remarks -- Acknowledgements -- References -- Chapter 3 Efficient ECL Luminophores -- 3.1 Introduction -- 3.2 Inorganic Systems -- 3.2.1 Ru(bpy)3 2+ and Its Derivatives -- 3.2.2 Cyclometalated Iridium(III) Complexes -- 3.2.3 Other Metal Complexes -- 3.3 Organic Systems -- 3.3.1 Polycyclic Aromatic Hydrocarbons (PAHs) -- 3.3.2 Fluorescent Dyes and their Derivatives -- 3.4 Conclusion -- References -- Chapter 4 Electrochemiluminescence Coreactants -- 4.1 Introduction -- 4.2 Oxidative-Reduction Coreactants -- 4.2.1 Oxalate (C2O42-) System -- 4.2.2 Tri-n-propylamine (TPA) -- 4.2.3 2-(Dibutylamino)ethanol (DBAE) -- 4.2.4 Other Amine-related Coreactants -- 4.2.5 Organic Acids/Alcohols and Relative Derivatives -- 4.2.6 QDs -- 4.2.7 Sulphite -- 4.3 Reductive-Oxidative Coreactants -- 4.3.1 Peroxydisulfate -- 4.3.2 Oxygen -- 4.3.3 Hydrogen Peroxide -- 4.4 Conclusions -- Acknowledgements..
| Medienart: |
E-Book |
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| Erscheinungsjahr: |
2019 ©2020 |
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| Erschienen: |
Cambridge: Royal Society of Chemistry ; 2019 ©2020 |
| Weitere Ausgaben: |
Erscheint auch als Druck-Ausgabe: Analytical electrogenerated chemiluminescence |
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| Reihe: |
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| Sprache: |
Englisch |
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| Beteiligte Personen: |
Sojic, Neso [HerausgeberIn] |
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| Links: |
ebookcentral.proquest.com [lizenzpflichtig] |
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| ISBN: |
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| BKL: | |
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| Themen: |
Chemiluminescence |
| Anmerkungen: |
Description based on publisher supplied metadata and other sources |
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| Umfang: |
1 Online-Ressource (516 Seitee) |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
1686206135 |
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| 520 | |a Book is ideal for graduate students, academics and researchers in industry looking for a comprehensive guide to the different aspects of electrogenerated chemiluminescence. | ||
| 520 | |a Cover -- Preface -- Contents -- Chapter 1 Introduction and Overview of Electrogenerated Chemiluminescence -- 1.1 Introduction -- 1.2 Fundamentals of Electrochemistry and Photophysics for ECL -- 1.2.1 Basic Electrochemical Principles -- 1.2.2 Basic Photophysical Principles -- 1.2.3 Energetics and Kinetics -- 1.3 Mechanistic Pathways of ECL -- 1.3.1 Electron-transfer Reactions Involving the Luminophore -- 1.3.2 Bond-breaking Reactions Within the Luminophore Frame -- 1.3.3 Hot Electron-induced ECL -- 1.4 Key Protagonists in the ECL -- 1.4.1 Luminophores -- 1.4.2 Coreactants -- 1.4.3 Electrode Materials -- 1.5 Analytical Applications -- 1.5.1 Analytical Strategies -- 1.5.2 Bioassays -- 1.6 Conclusion -- References -- Chapter 2 Energetic and Kinetic Aspects of ECL Generation -- 2.1 Introduction -- 2.2 Energetics of ECL Reactants Annihilation -- 2.3 ECL Emission from the Lowest Excited Triplet State -- 2.4 ECL Emission from the Lowest Excited Singlet State -- 2.5 Concluding Remarks -- Acknowledgements -- References -- Chapter 3 Efficient ECL Luminophores -- 3.1 Introduction -- 3.2 Inorganic Systems -- 3.2.1 Ru(bpy)3 2+ and Its Derivatives -- 3.2.2 Cyclometalated Iridium(III) Complexes -- 3.2.3 Other Metal Complexes -- 3.3 Organic Systems -- 3.3.1 Polycyclic Aromatic Hydrocarbons (PAHs) -- 3.3.2 Fluorescent Dyes and their Derivatives -- 3.4 Conclusion -- References -- Chapter 4 Electrochemiluminescence Coreactants -- 4.1 Introduction -- 4.2 Oxidative-Reduction Coreactants -- 4.2.1 Oxalate (C2O42-) System -- 4.2.2 Tri-n-propylamine (TPA) -- 4.2.3 2-(Dibutylamino)ethanol (DBAE) -- 4.2.4 Other Amine-related Coreactants -- 4.2.5 Organic Acids/Alcohols and Relative Derivatives -- 4.2.6 QDs -- 4.2.7 Sulphite -- 4.3 Reductive-Oxidative Coreactants -- 4.3.1 Peroxydisulfate -- 4.3.2 Oxygen -- 4.3.3 Hydrogen Peroxide -- 4.4 Conclusions -- Acknowledgements. | ||
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