Catalysis / editors James J. Spivey (Louisiana State University, USA), Yi-Fan Han (East China University of Science and Technology, Shanghai, China) ; authors M. V. Arapova (Boreskov Institute of Catalysis, Russia),L. N. Bobrova (Boreskov Institute of Catalysis, Russia)

Cover; Preface; Author biographies; Contents; Catalytic Conversion of Biomass-derived Compounds to C4 Chemicals; 1 Introduction; 2 Biomass-derived platform chemicals for C4 chemical production; 2.1 Succinic acid; 2.2 2,3-Butanediol (23BDO); 2.3 1,3-Butanediol (13BDO); 3 C4 Products; 3.1 1,4-Butanediol (14BDO); 3.2 Gamma-butyrolactone (GBL); 3.3 Tetrahydrofuran (THF); 3.4 1,3-Butadiene (BD); 3.4.1 Ethanol to BD; 3.4.2 23BDO to BD; 3.4.3 13BDO to BD; 3.4.4 14BDO to BD; 3.5 Butene; 3.6 2,3-Butanedione; 3.6.1 MEK to 2,3-Butanedione; 3.6.2 23BDO to 2,3-Butanedione; 3.7 MEK; 3.8 n-Butanol.

3.8.1 Guerbet reaction3.8.2 Direct synthesis; 3.9 Isobutanol; 4 Conclusion; References; Catalytic wet oxidation: process and catalyst development and the application perspective; 1 Introduction; 2 CWO processes; 2.1 Homogeneous CWO processes; 2.1.1 Loprox process; 2.1.2 Ciba-Geigy process; 2.1.3 IT EnviroScience process; 2.1.4 ATHOS process; 2.1.5 ORCAN process; 2.2 Heterogeneous CWO processes; 2.2.1 Osaka gas process; 2.2.2 Nippon Shokubai process; 2.2.3 Kurita processes; 2.2.4 CALIPHOX process; 2.2.5 DICP process; 2.2.6 Watercatox process; 3 CWO catalysts; 3.1 Homogeneous CWO catalysts.

3.2 Heterogeneous CWO catalysts3.2.1 Noble metal catalysts; 3.2.1.1 Pt based catalysts; 3.2.1.2 Ru based catalysts; 3.2.1.3 Pd based catalysts; 3.2.1.4 Au, Ag, Ir and Rh based catalysts; 3.2.2 Non-noble metal catalysts; 3.2.2.1 Cu based catalysts; 3.2.2.2 Fe based catalysts; 3.2.2.3 Ni based catalysts; 3.2.2.4 Mo based catalysts; 3.2.2.5 Ce based catalysts; 3.2.3 Preparation of CWO catalysts; 4 The application perspective of CWO -- a case study; 4.1 Properties of the pyrolysis wastewater; 4.2 Treatment of the pyrolysis wastewater; 4.3 CWO of the pyrolysis wastewater; 5 Conclusions.

AcknowledgmentsReferences; Opportunities for controlling catalysis by designing molecular environments around active sites: cations supported on amorphous versus crystalline zeolitic silicate supports; 1 Introduction; 2 The molecular environment of a grafted cation active site on a silicate surface: inner- vs. outer-spheres; 2.1 The architecture of an active site: inner-sphere vs. outer-spheres; 2.2 Inner-sphere vs. outer-sphere effects on catalysis: Brønsted acid catalysis by aluminosilicates; 2.2.1 Overview; 2.2.2 Effects of inner-sphere environments.

2.2.3 Effects of outer-sphere environments3 Amorphous vs. crystalline zeolitic silicates: supports of identical composition but different structural environments; 3.1 Amorphous silica (SiO2): a disordered support; 3.2 Zeotypes: well-ordered supports; 3.3 Silanols on amorphous silica vs. crystalline zeotype silicates; 3.4 Structural rearrangements of silicates: mechanical rigidity in amorphous vs. zeotype silicates; 4 High external-surface zeotype supports: delaminated zeotypes; 5 Challenges in controlling the incorporation of cations into silicates: a case study of TiIV and FeIII.

This volume looks at modern approaches to catalysis and reviews the extensive literature including direct methane conversion, nanocomposite catalysts for transformation of biofuels into syngas and hydrogen, and catalytic wet air oxidation technology for industrial wastewater treatment.

Medienart:	E-Book

Erscheinungsjahr:	2019 [2019] © 2019
Erschienen:	Cambridge: Royal Society of Chemistry ; 2019 London: Royal Society of Chemistry ; 2019 © 2019

Reihe:	Catalysis - volume 31 RSC catalysis series A specialist periodical report

Sprache:	Englisch

Beteiligte Personen:	Spivey, James [HerausgeberIn] Han, Yi-Fan [HerausgeberIn]

Links:	Volltext Inhaltsverzeichnis

ISBN:	978-1-78801-697-1 1-78801-697-1 978-1-78801-696-4 1-78801-696-3

Themen:	Catalysis SCIENCE ; Chemistry ; Physical & Theoretical

Umfang:	1 Online-Ressource (346 Seiten) ; Illustrationen

doi:	10.1039/9781788016971

funding:
Förderinstitution / Projekttitel:

PPN (Katalog-ID):	1662516290