Palladium-catalyzed oxidative deacetonative coupling of 4-aryl-2-methyl-3-butyn-2-ols with H-phosphonates

An efficient and generally applicable protocol for palladium-catalyzed oxidative deacetonative coupling of 4-aryl-2-methyl-3-butyn-2-ols with dialkyl H-phosphonates has been developed. This methodology provides a new and practical route to alkynylphosphonates using the inexpensive 4-aryl-2-methyl-3-butyn-2-ols as the alkyne sources. This reaction could also be performed with aryl bromides, 2-methyl-3-butyne-2-ol and dialkyl H-phosphonates using the cheap 2-methyl-3-butyne-2-ol as an alkyne source..

Medienart:

Artikel

Erscheinungsjahr:

2015

Erschienen:

2015

Enthalten in:

Zur Gesamtaufnahme - volume:13

Enthalten in:

Organic & biomolecular chemistry - 13(2015), 8, Seite 2432

Sprache:

Englisch

Beteiligte Personen:

Li, Xiang [VerfasserIn]
Wu, Yangjie [Sonstige Person]
Sun, Suyan [Sonstige Person]
Kang, Jianxun [Sonstige Person]
Wu, Yusheng [Sonstige Person]
Yang, Fan [Sonstige Person]

Links:

www.ncbi.nlm.nih.gov

BKL:

35.50

35.70

Themen:

Butanols - chemistry
Organometallic Compounds - chemistry
Organophosphonates - chemistry
Palladium - chemistry

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

OLC1970238968