Porphyrin(2.1.2.1) as a novel binucleating ligand : synthesis and molecular structures of mono- and di-rhodium(I) complexes
The first example of monovalent and bimetallic porphyrins(2.1.2.1), the rhodium(I) complex of porphyrin(2.1.2.1), was readily obtained under controlled conditions. The coordinated rhodium(I) drastically influenced the molecular structure and optical and electronic properties. Our results clearly demonstrate that porphyrin(2.1.2.1) could be developed as a new binucleating ligand for the fabrication of bimetallic complexes.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2021 |
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| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:57 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 57(2021), 95 vom: 30. Nov., Seite 12808-12811 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Xue, Songlin [VerfasserIn] |
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| Links: |
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| Anmerkungen: |
Date Revised 01.12.2021 published: Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d1cc05641g |
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| funding: |
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| Förderinstitution / Projekttitel: |
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NLM333215206 |
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| 500 | |a Date Revised 01.12.2021 | ||
| 500 | |a published: Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a The first example of monovalent and bimetallic porphyrins(2.1.2.1), the rhodium(I) complex of porphyrin(2.1.2.1), was readily obtained under controlled conditions. The coordinated rhodium(I) drastically influenced the molecular structure and optical and electronic properties. Our results clearly demonstrate that porphyrin(2.1.2.1) could be developed as a new binucleating ligand for the fabrication of bimetallic complexes | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Liu, Ningchao |e verfasserin |4 aut | |
| 700 | 1 | |a Mei, Peifeng |e verfasserin |4 aut | |
| 700 | 1 | |a Kuzuhara, Daiki |e verfasserin |4 aut | |
| 700 | 1 | |a Zhou, Mingbo |e verfasserin |4 aut | |
| 700 | 1 | |a Pan, Jianming |e verfasserin |4 aut | |
| 700 | 1 | |a Yamada, Hiroko |e verfasserin |4 aut | |
| 700 | 1 | |a Qiu, Fengxian |e verfasserin |4 aut | |
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