Sodium silylsilanolate enables nickel-catalysed silylation of aryl chlorides
Structurally diverse aryl chlorides were silylated with sodium silylsilanolate reagents in the presence of a Ni(cod)2 catalyst complexed with a phosphine ligand; PMe2Ph for electron-rich substrates, and PCy2Ph for electron-deficient ones. The mild reaction conditions allowed the silylation of various aryl chlorides including functionalised drug molecules.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2021 |
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| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:57 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 57(2021), 56 vom: 13. Juli, Seite 6867-6870 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Hitoshio, Kenshiro [VerfasserIn] |
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| Anmerkungen: |
Date Completed 13.07.2021 Date Revised 13.07.2021 published: Print Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/d1cc02683f |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM327279532 |
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| 520 | |a Structurally diverse aryl chlorides were silylated with sodium silylsilanolate reagents in the presence of a Ni(cod)2 catalyst complexed with a phosphine ligand; PMe2Ph for electron-rich substrates, and PCy2Ph for electron-deficient ones. The mild reaction conditions allowed the silylation of various aryl chlorides including functionalised drug molecules | ||
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| 700 | 1 | |a Shimokawa, Jun |e verfasserin |4 aut | |
| 700 | 1 | |a Yorimitsu, Hideki |e verfasserin |4 aut | |
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