On-surface isostructural transformation from a hydrogen-bonded network to a coordination network for tuning the pore size and guest recognition
This journal is © The Royal Society of Chemistry..
Rational manipulation of supramolecular structures on surfaces is of great importance and challenging. We show that imidazole-based hydrogen-bonded networks on a metal surface can transform into an isostructural coordination network for facile tuning of the pore size and guest recognition behaviours. Deposition of triangular-shaped benzotrisimidazole (H3btim) molecules on Au(111)/Ag(111) surfaces gives honeycomb networks linked by double N-H⋯N hydrogen bonds. While the H3btim hydrogen-bonded networks on Au(111) evaporate above 453 K, those on Ag(111) transform into isostructural [Ag3(btim)] coordination networks based on double N-Ag-N bonds at 423 K, by virtue of the unconventional metal-acid replacement reaction (Ag reduces H+). The transformation expands the pore diameter of the honeycomb networks from 3.8 Å to 6.9 Å, giving remarkably different host-guest recognition behaviours for fullerene and ferrocene molecules based on the size compatibility mechanism.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2020 |
|---|---|
| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:12 |
|---|---|
| Enthalten in: |
Chemical science - 12(2020), 4 vom: 13. Nov., Seite 1272-1277 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Zhou, Dong-Dong [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
|---|
| Anmerkungen: |
Date Revised 04.04.2024 published: Electronic Citation Status PubMed-not-MEDLINE |
|---|
| doi: |
10.1039/d0sc05147k |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM327111542 |
|---|
| LEADER | 01000caa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM327111542 | ||
| 003 | DE-627 | ||
| 005 | 20240404232447.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1039/d0sc05147k |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1364.xml |
| 035 | |a (DE-627)NLM327111542 | ||
| 035 | |a (NLM)34163889 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Zhou, Dong-Dong |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a On-surface isostructural transformation from a hydrogen-bonded network to a coordination network for tuning the pore size and guest recognition |
| 264 | 1 | |c 2020 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Revised 04.04.2024 | ||
| 500 | |a published: Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a This journal is © The Royal Society of Chemistry. | ||
| 520 | |a Rational manipulation of supramolecular structures on surfaces is of great importance and challenging. We show that imidazole-based hydrogen-bonded networks on a metal surface can transform into an isostructural coordination network for facile tuning of the pore size and guest recognition behaviours. Deposition of triangular-shaped benzotrisimidazole (H3btim) molecules on Au(111)/Ag(111) surfaces gives honeycomb networks linked by double N-H⋯N hydrogen bonds. While the H3btim hydrogen-bonded networks on Au(111) evaporate above 453 K, those on Ag(111) transform into isostructural [Ag3(btim)] coordination networks based on double N-Ag-N bonds at 423 K, by virtue of the unconventional metal-acid replacement reaction (Ag reduces H+). The transformation expands the pore diameter of the honeycomb networks from 3.8 Å to 6.9 Å, giving remarkably different host-guest recognition behaviours for fullerene and ferrocene molecules based on the size compatibility mechanism | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Wang, Jun |e verfasserin |4 aut | |
| 700 | 1 | |a Chen, Pin |e verfasserin |4 aut | |
| 700 | 1 | |a He, Yangyong |e verfasserin |4 aut | |
| 700 | 1 | |a Wu, Jun-Xi |e verfasserin |4 aut | |
| 700 | 1 | |a Gao, Sen |e verfasserin |4 aut | |
| 700 | 1 | |a Zhong, Zhihao |e verfasserin |4 aut | |
| 700 | 1 | |a Du, Yunfei |e verfasserin |4 aut | |
| 700 | 1 | |a Zhong, Dingyong |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Jie-Peng |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Chemical science |d 2010 |g 12(2020), 4 vom: 13. Nov., Seite 1272-1277 |w (DE-627)NLM204906237 |x 2041-6520 |7 nnns |
| 773 | 1 | 8 | |g volume:12 |g year:2020 |g number:4 |g day:13 |g month:11 |g pages:1272-1277 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1039/d0sc05147k |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 12 |j 2020 |e 4 |b 13 |c 11 |h 1272-1277 | ||