At Long Last : The Me3 Si Group as a Masked Alcohol
© 2021 Wiley-VCH GmbH..
For a long time, the Me3 Si group has been ostracized from the family of aryl- and heteroatom-substituted congeners for the difficulties associated with its further chemoselective manipulation into another synthetically useful functional group. A hypervalent iodine reagent has now been shown to do exactly that by electrophilic demethylation. Coupled with the Tamao-Fleming oxidation, the Me3 Si group becomes a placeholder for a hydroxy group.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2021 |
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| Erschienen: |
2021 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:60 |
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| Enthalten in: |
Angewandte Chemie (International ed. in English) - 60(2021), 9 vom: 23. Feb., Seite 4408-4410 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Roy, Avijit [VerfasserIn] |
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| Links: |
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| Themen: |
Alcohols |
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| Anmerkungen: |
Date Revised 26.03.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1002/anie.202017157 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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NLM32058934X |
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| 520 | |a For a long time, the Me3 Si group has been ostracized from the family of aryl- and heteroatom-substituted congeners for the difficulties associated with its further chemoselective manipulation into another synthetically useful functional group. A hypervalent iodine reagent has now been shown to do exactly that by electrophilic demethylation. Coupled with the Tamao-Fleming oxidation, the Me3 Si group becomes a placeholder for a hydroxy group | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a Review | |
| 650 | 4 | |a Tamao-Fleming oxidation | |
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| 650 | 4 | |a density functional calculations | |
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