Catalytic O2 activation with synthetic models of α-ketoglutarate dependent oxygenases
An iron complex bearing the facially capping tridentate 1,4,7-triazacyclononane ligand mimics structural and functional features of alpha-ketoglutarate (α-KG) dependent enzymes, and engages in enzyme-like catalytic O2 activation coupled to α-ketoacid decarboxylation, oxygenating sulfides. This system constitutes a rare case of non-enzymatic catalytic O2 activation, cycling between FeII and FeIV(O).
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2020 |
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| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:56 |
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| Enthalten in: |
Chemical communications (Cambridge, England) - 56(2020), 92 vom: 19. Nov., Seite 14369-14372 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Sánchez-Eguía, Brenda N [VerfasserIn] |
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| Links: |
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| Themen: |
Coordination Complexes |
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| Anmerkungen: |
Date Completed 25.05.2021 Date Revised 25.05.2021 published: Print Citation Status MEDLINE |
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| doi: |
10.1039/d0cc05942k |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM317185179 |
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| 500 | |a published: Print | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a An iron complex bearing the facially capping tridentate 1,4,7-triazacyclononane ligand mimics structural and functional features of alpha-ketoglutarate (α-KG) dependent enzymes, and engages in enzyme-like catalytic O2 activation coupled to α-ketoacid decarboxylation, oxygenating sulfides. This system constitutes a rare case of non-enzymatic catalytic O2 activation, cycling between FeII and FeIV(O) | ||
| 650 | 4 | |a Journal Article | |
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| 650 | 7 | |a Ferrous Compounds |2 NLM | |
| 650 | 7 | |a Ketoglutaric Acids |2 NLM | |
| 650 | 7 | |a Ligands |2 NLM | |
| 650 | 7 | |a Sulfides |2 NLM | |
| 650 | 7 | |a Oxygenases |2 NLM | |
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| 700 | 1 | |a Company, Anna |e verfasserin |4 aut | |
| 700 | 1 | |a Costas, Miquel |e verfasserin |4 aut | |
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