Improved High Rate and Temperature Stability Using an Anisotropically Aligned Pillar-Type Solid Electrolyte Interphase for Lithium-Ion Batteries
Numerous reports have elucidated the advantages of SiOx-based anodes including their large capacities and superior cycling stabilities. However, these electrodes have not been optimized for use in electric vehicles (EVs), which demand even better performance stability at fast charging rates and high temperatures. Herein, we fabricated a novel solid electrolyte interphase (SEI) using nanodiamondseeds. The grown SEI comprised an assembly of pillars, with a height and diameter of approximately 600 and 250 nm, respectively. As a result, the Li||Ti-SiOxC cell with a nanodiamond-containing electrolyte achieved a high capacity retention of 76.4% over 1000 cycles at 5 A g-1 and 50 °C, whereas the cell with no nanodiamond seeds showed a severe decay in the capacity and retained only 61.5% of its initial capacity. Furthermore, the NCM811||Ti-SiOx@C full cell constructed with the pillar-type SEI also showed a high capacity retention of 61.8% at 5 C (1 C = 200 mAh g-1) and 50 °C after 500 cycles, which was a significant improvement from the value (33.3%) demonstrated by its counterpart comprising the conventional SEI. The results obtained herein will enable the development of high-performance lithium-ion batteries.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2020 |
|---|---|
| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:12 |
|---|---|
| Enthalten in: |
ACS applied materials & interfaces - 12(2020), 38 vom: 23. Sept., Seite 42781-42789 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Yang, Hyeon-Woo [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
Journal Article |
|---|
| Anmerkungen: |
Date Revised 24.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
|---|
| doi: |
10.1021/acsami.0c11068 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM314137580 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM314137580 | ||
| 003 | DE-627 | ||
| 005 | 20231225152105.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/acsami.0c11068 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1047.xml |
| 035 | |a (DE-627)NLM314137580 | ||
| 035 | |a (NLM)32840346 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Yang, Hyeon-Woo |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Improved High Rate and Temperature Stability Using an Anisotropically Aligned Pillar-Type Solid Electrolyte Interphase for Lithium-Ion Batteries |
| 264 | 1 | |c 2020 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Revised 24.09.2020 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a Numerous reports have elucidated the advantages of SiOx-based anodes including their large capacities and superior cycling stabilities. However, these electrodes have not been optimized for use in electric vehicles (EVs), which demand even better performance stability at fast charging rates and high temperatures. Herein, we fabricated a novel solid electrolyte interphase (SEI) using nanodiamondseeds. The grown SEI comprised an assembly of pillars, with a height and diameter of approximately 600 and 250 nm, respectively. As a result, the Li||Ti-SiOxC cell with a nanodiamond-containing electrolyte achieved a high capacity retention of 76.4% over 1000 cycles at 5 A g-1 and 50 °C, whereas the cell with no nanodiamond seeds showed a severe decay in the capacity and retained only 61.5% of its initial capacity. Furthermore, the NCM811||Ti-SiOx@C full cell constructed with the pillar-type SEI also showed a high capacity retention of 61.8% at 5 C (1 C = 200 mAh g-1) and 50 °C after 500 cycles, which was a significant improvement from the value (33.3%) demonstrated by its counterpart comprising the conventional SEI. The results obtained herein will enable the development of high-performance lithium-ion batteries | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a SiOx-based anode | |
| 650 | 4 | |a lithium-ion battery | |
| 650 | 4 | |a nanodiamond-containing electrolyte | |
| 650 | 4 | |a pillar-type morphology | |
| 650 | 4 | |a solid electrolyte interphase | |
| 700 | 1 | |a Munisamy, Maniyazagan |e verfasserin |4 aut | |
| 700 | 1 | |a Kwon, Myoung Taek |e verfasserin |4 aut | |
| 700 | 1 | |a Kang, Woo Seung |e verfasserin |4 aut | |
| 700 | 1 | |a Kim, Sun-Jae |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t ACS applied materials & interfaces |d 2009 |g 12(2020), 38 vom: 23. Sept., Seite 42781-42789 |w (DE-627)NLM194100049 |x 1944-8252 |7 nnns |
| 773 | 1 | 8 | |g volume:12 |g year:2020 |g number:38 |g day:23 |g month:09 |g pages:42781-42789 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1021/acsami.0c11068 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 12 |j 2020 |e 38 |b 23 |c 09 |h 42781-42789 | ||