Chrysene-Based Blue Emitters
© 2020 The Authors. Published by Wiley-VCH GmbH..
Chrysene and its bisbenzannulated homologue, naphtho[2,3-c]tetraphene, were synthesized through a PtCl2 -catalyzed cyclization of alkynes, which also furnished corresponding biaryls subsequent to a Glaser coupling reaction of the starting alkynes. The optoelectronic properties of 5,5'-bichrysenyl and 6,6'-binaphtho[2,3-c]tetraphene were compared to their chrysene-based "monomers". Oxidative cyclodehydrogenations of bichrysenyl and its higher homologue towards large nanographenes were also investigated.
Medienart: |
E-Artikel |
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Erscheinungsjahr: |
2020 |
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Erschienen: |
2020 |
Enthalten in: |
Zur Gesamtaufnahme - volume:26 |
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Enthalten in: |
Chemistry (Weinheim an der Bergstrasse, Germany) - 26(2020), 66 vom: 26. Nov., Seite 15089-15093 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Nathusius, Marvin [VerfasserIn] |
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Links: |
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Themen: |
2D acenes |
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Anmerkungen: |
Date Revised 29.12.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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doi: |
10.1002/chem.202001808 |
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funding: |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM31316391X |
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520 | |a Chrysene and its bisbenzannulated homologue, naphtho[2,3-c]tetraphene, were synthesized through a PtCl2 -catalyzed cyclization of alkynes, which also furnished corresponding biaryls subsequent to a Glaser coupling reaction of the starting alkynes. The optoelectronic properties of 5,5'-bichrysenyl and 6,6'-binaphtho[2,3-c]tetraphene were compared to their chrysene-based "monomers". Oxidative cyclodehydrogenations of bichrysenyl and its higher homologue towards large nanographenes were also investigated | ||
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