Cu(II)-Catalyzed 6π-Photocyclization of Non-6π Substrates
This research successfully achieved a Cu(II)-catalyzed 6π-photocyclization of non-6π substrates. The photoenolization converts ortho-alkylphenyl alkynl ketones into a triene-type intermediate which undergoes the subsequent 6π-photocyclization to give naphthol as the final product. Cu(II) catalyst facilitates both photoenolization and 6π-photocyclization. This research highlighted the tandem reaction strategy and the importance of metal catalysis in photochemistry.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2020 |
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| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:22 |
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| Enthalten in: |
Organic letters - 22(2020), 14 vom: 17. Juli, Seite 5502-5505 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Zhang, Yanbin [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 28.09.2020 Date Revised 28.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1021/acs.orglett.0c01854 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM31162927X |
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| 520 | |a This research successfully achieved a Cu(II)-catalyzed 6π-photocyclization of non-6π substrates. The photoenolization converts ortho-alkylphenyl alkynl ketones into a triene-type intermediate which undergoes the subsequent 6π-photocyclization to give naphthol as the final product. Cu(II) catalyst facilitates both photoenolization and 6π-photocyclization. This research highlighted the tandem reaction strategy and the importance of metal catalysis in photochemistry | ||
| 650 | 4 | |a Journal Article | |
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