CoreSatellite Janus Nanomotors with pH-Responsive Multi-phoretic Propulsion

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim..

We report coresatellite Janus mesoporous silica-Pt@Au (JMPA) nanomotors with pH-responsive multi-phoretic propulsion. The JMPA nanomotors first undergo self-diffusiophoretic propulsion in 3.0 % H2 O2 due to the isolation of the Au nanoparticles (AuNPs) from the PtNPs layer. Then the weak acidity of H2 O2 can trigger the disassembly and reassembly of the AuNPs, resulting in the Janus distribution of large AuNPs aggregates. Such reconstruction of JMPA leads to the contact between PtNPs and AuNPs aggregates, thus changing the propulsion mechanism to self-electrophoresis. The asymmetric and aggregated AuNPs also enable the generation of a thermal gradient under laser irradiation, which propels the JMPA nanomotors by self-thermophoresis. Such multi-phoretic propulsion offers considerable promise for developing advanced nanomachines with a stimuli-responsive switch of propulsion modes in biomedical applications.

Medienart:

E-Artikel

Erscheinungsjahr:

2020

Erschienen:

2020

Enthalten in:

Zur Gesamtaufnahme - volume:59

Enthalten in:

Angewandte Chemie (International ed. in English) - 59(2020), 34 vom: 17. Aug., Seite 14368-14372

Sprache:

Englisch

Beteiligte Personen:

Xing, Yi [VerfasserIn]
Zhou, Mengyun [VerfasserIn]
Xu, Tailin [VerfasserIn]
Tang, Songsong [VerfasserIn]
Fu, Yang [VerfasserIn]
Du, Xin [VerfasserIn]
Su, Lei [VerfasserIn]
Wen, Yongqiang [VerfasserIn]
Zhang, Xueji [VerfasserIn]
Ma, Tianyi [VerfasserIn]

Links:

Volltext

Themen:

Core-satellite nanoparticles
Journal Article
Nanomotors
PH response
Phoretic propulsion
Photothermal effect
Research Support, Non-U.S. Gov't

Anmerkungen:

Date Completed 11.12.2020

Date Revised 14.12.2020

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.1002/anie.202006421

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM310862965