Formation of a dimeric tungsten(i) complex via C-H activation
An aminopyridinato ligand stabilized and coordinatively unsaturated dimeric tungsten(0) complex having an electronic structure with six metal centred HOMOs (σ2,π2,π2,δ2,δ2, and δ*2) has been isolated and structurally characterized. Its reaction with a cryptand leads to a C-H bond activation of one of the isopropyl groups of the N-ligand to form a dimeric tungsten(i) complex.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2020 |
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| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:49 |
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| Enthalten in: |
Dalton transactions (Cambridge, England : 2003) - 49(2020), 6 vom: 14. Feb., Seite 1992-1996 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Noor, Awal [VerfasserIn] |
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| Links: |
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| Anmerkungen: |
Date Revised 12.02.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/c9dt04847b |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM305815237 |
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| 520 | |a An aminopyridinato ligand stabilized and coordinatively unsaturated dimeric tungsten(0) complex having an electronic structure with six metal centred HOMOs (σ2,π2,π2,δ2,δ2, and δ*2) has been isolated and structurally characterized. Its reaction with a cryptand leads to a C-H bond activation of one of the isopropyl groups of the N-ligand to form a dimeric tungsten(i) complex | ||
| 650 | 4 | |a Journal Article | |
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| 700 | 1 | |a Schwarz, Stefan |e verfasserin |4 aut | |
| 700 | 1 | |a Dietel, Thomas |e verfasserin |4 aut | |
| 700 | 1 | |a Kempe, Rhett |e verfasserin |4 aut | |
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