Effect of disorder and polarization sequences on two-dimensional spectra of light-harvesting complexes
Two-dimensional electronic spectra (2DES) provide unique ways to track the energy transfer dynamics in light-harvesting complexes. The interpretation of the peaks and structures found in experimentally recorded 2DES is often not straightforward, since several processes are imaged simultaneously. The choice of specific pulse polarization sequences helps to disentangle the sometimes convoluted spectra, but brings along other disturbances. We show by detailed theoretical calculations how 2DES of the Fenna-Matthews-Olson complex are affected by rotational and conformational disorder of the chromophores.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2020 |
|---|---|
| Erschienen: |
2020 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:144 |
|---|---|
| Enthalten in: |
Photosynthesis research - 144(2020), 2 vom: 23. Mai, Seite 147-154 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Kramer, Tobias [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
FMO (Fenna–Matthews–Olson complex) |
|---|
| Anmerkungen: |
Date Completed 14.04.2021 Date Revised 14.04.2021 published: Print-Electronic Citation Status MEDLINE |
|---|
| doi: |
10.1007/s11120-019-00699-6 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM304725765 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM304725765 | ||
| 003 | DE-627 | ||
| 005 | 20231225115612.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231225s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1007/s11120-019-00699-6 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n1015.xml |
| 035 | |a (DE-627)NLM304725765 | ||
| 035 | |a (NLM)31872335 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Kramer, Tobias |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Effect of disorder and polarization sequences on two-dimensional spectra of light-harvesting complexes |
| 264 | 1 | |c 2020 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 14.04.2021 | ||
| 500 | |a Date Revised 14.04.2021 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a Two-dimensional electronic spectra (2DES) provide unique ways to track the energy transfer dynamics in light-harvesting complexes. The interpretation of the peaks and structures found in experimentally recorded 2DES is often not straightforward, since several processes are imaged simultaneously. The choice of specific pulse polarization sequences helps to disentangle the sometimes convoluted spectra, but brings along other disturbances. We show by detailed theoretical calculations how 2DES of the Fenna-Matthews-Olson complex are affected by rotational and conformational disorder of the chromophores | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a FMO (Fenna–Matthews–Olson complex) | |
| 650 | 4 | |a Light-harvesting complex | |
| 650 | 4 | |a Two-dimensional spectroscopy | |
| 650 | 7 | |a Light-Harvesting Protein Complexes |2 NLM | |
| 700 | 1 | |a Rodríguez, Mirta |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Photosynthesis research |d 1980 |g 144(2020), 2 vom: 23. Mai, Seite 147-154 |w (DE-627)NLM114361657 |x 1573-5079 |7 nnns |
| 773 | 1 | 8 | |g volume:144 |g year:2020 |g number:2 |g day:23 |g month:05 |g pages:147-154 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1007/s11120-019-00699-6 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 144 |j 2020 |e 2 |b 23 |c 05 |h 147-154 | ||