On the Fourth Order Hamiltonian of an Asymmetric Rotor Molecule of Orthorhombic Symmetry

The fourth order Hamiltonian of an asymmetric rotor molecule of orthorhombic symmetry given recently has been considerably reduced in complexity through the use of equations derived from the basic relationship among the angular momentum operators. The reduced Hamiltonian obtained provides a most convenient starting point for the calculation of rotational energy levels from a solution of the complete secular equation, for a perturbation theory solution to the problem of centrifugal distortion, and for the deduction of sum rules among the energy levels.

Medienart:

E-Artikel

Erscheinungsjahr:

1963

Erschienen:

1963

Enthalten in:

Zur Gesamtaufnahme - volume:67A

Enthalten in:

Journal of research of the National Bureau of Standards. Section A, Physics and chemistry - 67A(1963), 4 vom: 24. Juli, Seite 359-362

Sprache:

Englisch

Beteiligte Personen:

Olson, Wm B [VerfasserIn]
Allen, H C [VerfasserIn]

Links:

Volltext

Themen:

Journal Article

Anmerkungen:

Date Revised 01.10.2020

published: Print-Electronic

Citation Status PubMed-not-MEDLINE

doi:

10.6028/jres.067A.039

funding:

Förderinstitution / Projekttitel:

PPN (Katalog-ID):

NLM301878560