Biodegradable Poly(ester- co-acrylate) with Antifoulant Pendant Groups for Marine Anti-Biofouling
Polymer resins are critical for marine anti-biofouling coatings. In this study, degradable poly(ester- co-acrylate) with antifoulant pendant groups has been prepared by the radical ring-opening polymerization of 2-methylene-1,3-dioxepane, methyl methacrylate, and N-methacryloyloxy methyl benzoisothiazolinone. Such a polymer containing main-chain esters can hydrolytically and enzymatically degrade. Both degradation rates increase with main-chain ester content. Moreover, since the antifoulant groups are chemically grafted to the degradable main chain, their release can be controlled by the degradation besides the hydrolysis of side groups. Our study shows that the copolymer coating is efficient in inhibiting the accumulation of marine bacterial biofilm of Pseudomonas sp. and diatom Navicular incerta. Marine field test reveals that the copolymer has excellent efficiency in preventing biofouling for more than 6 months.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2019 |
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| Erschienen: |
2019 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:11 |
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| Enthalten in: |
ACS applied materials & interfaces - 11(2019), 12 vom: 27. März, Seite 11947-11953 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Dai, Guoxiong [VerfasserIn] |
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| Links: |
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| Anmerkungen: |
Date Completed 12.07.2019 Date Revised 12.07.2019 published: Print-Electronic Citation Status MEDLINE |
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| doi: |
10.1021/acsami.9b01247 |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM29467621X |
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| 245 | 1 | 0 | |a Biodegradable Poly(ester- co-acrylate) with Antifoulant Pendant Groups for Marine Anti-Biofouling |
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| 500 | |a Date Revised 12.07.2019 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status MEDLINE | ||
| 520 | |a Polymer resins are critical for marine anti-biofouling coatings. In this study, degradable poly(ester- co-acrylate) with antifoulant pendant groups has been prepared by the radical ring-opening polymerization of 2-methylene-1,3-dioxepane, methyl methacrylate, and N-methacryloyloxy methyl benzoisothiazolinone. Such a polymer containing main-chain esters can hydrolytically and enzymatically degrade. Both degradation rates increase with main-chain ester content. Moreover, since the antifoulant groups are chemically grafted to the degradable main chain, their release can be controlled by the degradation besides the hydrolysis of side groups. Our study shows that the copolymer coating is efficient in inhibiting the accumulation of marine bacterial biofilm of Pseudomonas sp. and diatom Navicular incerta. Marine field test reveals that the copolymer has excellent efficiency in preventing biofouling for more than 6 months | ||
| 650 | 4 | |a Journal Article | |
| 650 | 4 | |a degradation | |
| 650 | 4 | |a marine anti-biofouling | |
| 650 | 4 | |a poly(ester-co-acrylate) | |
| 650 | 4 | |a polymeric antifoulant | |
| 650 | 4 | |a radical ring-opening polymerization | |
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| 700 | 1 | |a Xie, Qingyi |e verfasserin |4 aut | |
| 700 | 1 | |a Ma, Chunfeng |e verfasserin |4 aut | |
| 700 | 1 | |a Zhang, Guangzhao |e verfasserin |4 aut | |
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