Tetra-ethyl-ammonium hexa-cyanidoferrate(III) bis-(diaqua-{6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}manganese(III))-methanol-ethanol (1/2/2)
In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C(2) symmetric [Fe(CN)(6)](3-) anion and disordered methanol and ethanol solvent mol-ecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octa-hedral geometry with the coordination completed by two water mol-ecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent mol-ecules are connected into a zigzag chain through hydrogen-bonding inter-actions.
| Medienart: |
E-Artikel |
|---|
| Erscheinungsjahr: |
2009 |
|---|---|
| Erschienen: |
2009 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:65 |
|---|---|
| Enthalten in: |
Acta crystallographica. Section E, Structure reports online - 65(2009), Pt 11 vom: 17. Okt., Seite m1387-8 |
| Sprache: |
Englisch |
|---|
| Beteiligte Personen: |
Wang, Ting-Ting [VerfasserIn] |
|---|
| Links: |
|---|
| Themen: |
|---|
| Anmerkungen: |
Date Completed 14.07.2011 Date Revised 20.10.2021 published: Electronic Citation Status PubMed-not-MEDLINE |
|---|
| doi: |
10.1107/S1600536809037490 |
|---|
| funding: |
|
|---|---|
| Förderinstitution / Projekttitel: |
|
| PPN (Katalog-ID): |
NLM208287523 |
|---|
| LEADER | 01000naa a22002652 4500 | ||
|---|---|---|---|
| 001 | NLM208287523 | ||
| 003 | DE-627 | ||
| 005 | 20231224003722.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 231224s2009 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1107/S1600536809037490 |2 doi | |
| 028 | 5 | 2 | |a pubmed24n0694.xml |
| 035 | |a (DE-627)NLM208287523 | ||
| 035 | |a (NLM)21578133 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 100 | 1 | |a Wang, Ting-Ting |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Tetra-ethyl-ammonium hexa-cyanidoferrate(III) bis-(diaqua-{6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}manganese(III))-methanol-ethanol (1/2/2) |
| 264 | 1 | |c 2009 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ƒaComputermedien |b c |2 rdamedia | ||
| 338 | |a ƒa Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Date Completed 14.07.2011 | ||
| 500 | |a Date Revised 20.10.2021 | ||
| 500 | |a published: Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a In the title compound, (C(8)H(20)N)[Mn(C(22)H(18)N(2)O(4))(H(2)O)(2)][Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH or [NEt(4)][Mn(3-Meosalophen)(H(2)O)(2)](2)[Fe(CN)(6)]·2CH(3)OH·2C(2)H(5)OH, the asymmetric unit consists of one half of an [NEt(4)](+) cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H(2)O)(2)](+) coordination cation, one half of a C(2) symmetric [Fe(CN)(6)](3-) anion and disordered methanol and ethanol solvent mol-ecules that are equally populated at two different sites. The Mn(III) atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN(2)O(4) octa-hedral geometry with the coordination completed by two water mol-ecules. The [Mn(3-Meosalophen)(H(2)O)(2)](+) cations, [Fe(CN)(6)](3- )anions and solvent mol-ecules are connected into a zigzag chain through hydrogen-bonding inter-actions | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Xie, Ji-Min |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Acta crystallographica. Section E, Structure reports online |d 2005 |g 65(2009), Pt 11 vom: 17. Okt., Seite m1387-8 |w (DE-627)NLM164585273 |x 1600-5368 |7 nnns |
| 773 | 1 | 8 | |g volume:65 |g year:2009 |g number:Pt 11 |g day:17 |g month:10 |g pages:m1387-8 |
| 856 | 4 | 0 | |u http://dx.doi.org/10.1107/S1600536809037490 |3 Volltext |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a GBV_NLM | ||
| 951 | |a AR | ||
| 952 | |d 65 |j 2009 |e Pt 11 |b 17 |c 10 |h m1387-8 | ||