Chiral phosphonite, phosphite and phosphoramidite eta6-arene-ruthenium(II) complexes : application to the kinetic resolution of allylic alcohols
The synthesis and characterization of chiral arene-ruthenium complexes [RuCl(2)(eta(6)-arene){(R)-PR(binaphthoxy)}] (arene = benzene (1), p-cymene (2), mesitylene (3); R = Ph (a), OPh (b), piperidyl (c)) are described. Derivatives 1-3 have been employed to promote the kinetic resolution of allylic alcohols through a redox-isomerization process. As a general trend, the best selectivities are attained with the more sterically hindered catalysts i.e. those containing p-cymene or mesitylene ligands.
| Medienart: |
E-Artikel |
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| Erscheinungsjahr: |
2010 |
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| Erschienen: |
2010 |
| Enthalten in: |
Zur Gesamtaufnahme - volume:39 |
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| Enthalten in: |
Dalton transactions (Cambridge, England : 2003) - 39(2010), 33 vom: 07. Sept., Seite 7780-5 |
| Sprache: |
Englisch |
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| Beteiligte Personen: |
Fernández-Zúmel, Mariano A [VerfasserIn] |
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| Links: |
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| Themen: |
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| Anmerkungen: |
Date Completed 08.12.2010 Date Revised 11.08.2010 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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| doi: |
10.1039/c0dt00140f |
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| funding: |
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| Förderinstitution / Projekttitel: |
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| PPN (Katalog-ID): |
NLM199892814 |
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| 100 | 1 | |a Fernández-Zúmel, Mariano A |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Chiral phosphonite, phosphite and phosphoramidite eta6-arene-ruthenium(II) complexes |b application to the kinetic resolution of allylic alcohols |
| 264 | 1 | |c 2010 | |
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| 500 | |a Date Completed 08.12.2010 | ||
| 500 | |a Date Revised 11.08.2010 | ||
| 500 | |a published: Print-Electronic | ||
| 500 | |a Citation Status PubMed-not-MEDLINE | ||
| 520 | |a The synthesis and characterization of chiral arene-ruthenium complexes [RuCl(2)(eta(6)-arene){(R)-PR(binaphthoxy)}] (arene = benzene (1), p-cymene (2), mesitylene (3); R = Ph (a), OPh (b), piperidyl (c)) are described. Derivatives 1-3 have been employed to promote the kinetic resolution of allylic alcohols through a redox-isomerization process. As a general trend, the best selectivities are attained with the more sterically hindered catalysts i.e. those containing p-cymene or mesitylene ligands | ||
| 650 | 4 | |a Journal Article | |
| 700 | 1 | |a Lastra-Barreira, Beatriz |e verfasserin |4 aut | |
| 700 | 1 | |a Scheele, Marcus |e verfasserin |4 aut | |
| 700 | 1 | |a Díez, Josefina |e verfasserin |4 aut | |
| 700 | 1 | |a Crochet, Pascale |e verfasserin |4 aut | |
| 700 | 1 | |a Gimeno, José |e verfasserin |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Dalton transactions (Cambridge, England : 2003) |d 2004 |g 39(2010), 33 vom: 07. Sept., Seite 7780-5 |w (DE-627)NLM149339739 |x 1477-9234 |7 nnns |
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