Rhodium-catalyzed diarylation of oxalates using arylboron compounds
Dialkyl oxalates undergo selective diarylation on one of their carbonyl carbons upon treatment with arylboron reagents in the presence of a rhodium catalyst to give the corresponding alpha-hydroxydiarylacetates. Under similar conditions, the arylation of benzoylformate and benzil also proceeds efficiently.
Medienart: |
Artikel |
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Erscheinungsjahr: |
2007 |
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Erschienen: |
2007 |
Enthalten in: |
Zur Gesamtaufnahme - volume:72 |
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Enthalten in: |
The Journal of organic chemistry - 72(2007), 6 vom: 16. März, Seite 2255-7 |
Sprache: |
Englisch |
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Beteiligte Personen: |
Miyamura, Sawako [VerfasserIn] |
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Themen: |
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Anmerkungen: |
Date Completed 31.05.2007 Date Revised 09.03.2007 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
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Förderinstitution / Projekttitel: |
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PPN (Katalog-ID): |
NLM168498731 |
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520 | |a Dialkyl oxalates undergo selective diarylation on one of their carbonyl carbons upon treatment with arylboron reagents in the presence of a rhodium catalyst to give the corresponding alpha-hydroxydiarylacetates. Under similar conditions, the arylation of benzoylformate and benzil also proceeds efficiently | ||
650 | 4 | |a Journal Article | |
700 | 1 | |a Satoh, Tetsuya |e verfasserin |4 aut | |
700 | 1 | |a Miura, Masahiro |e verfasserin |4 aut | |
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